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New paleomagnetic constraints for the large-scale displacement of the Hronic nappe system of the Central Western Carpathians Emő Márton

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New paleomagnetic constraints for the large-scale displacement of the Hronic nappe system of the Central Western Carpathians

Emő Márton1, Jozef Madzin2, Dušan Plašienka3, Jacek Grabowski4, Jana Bučová2 5, Roman Aubrecht2 3 and Marián Putiš6

1 Mining and Geological Survey of Hungary, Paleomagnetic Laboratory, Columbus 17-23, H- 1145 Budapest, Hungary; paleo@mbfsz.gov.hu

2 Earth Science Institute, Slovak Academy of Sciences, Ďumbierska 1, 974 01 Banská Bystrica, Slovakia; jozef.madzin@savba.sk

3 Department of Geology and Paleontology, Faculty of Natural Sciences, Comenius University, Mlynská dolina, Ilkovičová 6, 842 15 Bratislava, Slovakia;

dusan.plasienka@uniba.sk; roman.aubrecht@uniba.sk

4 Polish Geological Institute – National Research Institute, Paleomagnetic Laboratory, Rakowiecka 4, 00-975 Warsaw, Poland; jgra@pgi.gov.pl

5 DPP Žilina Ltd, Legionárska 8203, 010 01 Žilina, Slovakia; jana.bucova@gmail.com

6 Comenius University, Faculty of Natural Sciences, Department of Mineralogy and Petrology, Ilkovičova 6, 842 15 Bratislava, Slovakia; marian.putis@uniba.sk

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Abstract

The thin-skinned Hronic nappe system represents the structurally highest tectonic unit in the Late Cretaceous thrust-stack of the Central Western Carpathians. It mostly comprises a Permian volcano-sedimentary sequence and Triassic carbonate sediments which crop out in different parts of the Central Western Carpathians. We carried out a systematic paleomagnetic study on 24 Permian and 20 Triassic localities geographically distributed over 300 km in W-E direction. Several samples from each locality were drilled and oriented in-situ and specimens cut from them subjected to standard paleomagnetic and magnetic mineralogy experiments.

The results were evaluated using principal component analysis, statistical evaluation of the characteristic remanences, and applying inclination-only and tilt tests. We documented the pre-tilting age of remanences for the majority of both the Permian and Triassic age groups.

However, the latter was interpreted as remagnetized during the Cretaceous Normal Super- Chron in the course of nappe stacking between 90-80 Ma. The Permian group is exhibiting about 70°, the Triassic about 34° clockwise vertical axis rotations with respect to the present north. There is no indication in our data set for oroclinal bending of the Hronic Unit. We interpret the difference in clockwise rotations (about 36°) between Permian and 90-80 Ma as a clockwise block rotation taking place during major extensional and/or compressive events between stable Europe and Africa. Taking into consideration the well-documented

counterclockwise rotation observed for the overstep sequences in the Central Western Carpathians and in the Pieniny Klippen Belt, the remagnetization of the Triassic sediments was closely followed by about 94° clockwise rotation. Research in progress will serve to decide if this large clockwise rotation involved the whole Central Carpathian nappe stack or part of this was due to the thin-skinned nappe emplacement of the Hronic Unit.

Key words: Central Western Carpathians, Hronic nappe Unit, Paleomagnetism, Remagnetization, Late Cretaceous, Tectonic rotations

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1. Introduction

The Western Carpathians form a northward convex, E-W trending mountain range, which is a part of the European Alpine orogenic system. Based on its structure and tectonic evolution it is divided into three main tectonic zones, namely the External, Central, and Internal Western Carpathians (Plašienka et al., 1997; Froitzheim et al., 2008; Plašienka, 2018). The Central Western Carpathians represent a nappe stack consisting of thick- and thin-skinned nappe units formed and thrust generally to the north-northwest (in recent coordinates) during the Late Cretaceous. The northern and northwestern part of the Central Western Carpathians, lying between the Čertovica thrust-fault and the Pieniny Klippen Belt (Fig. 1), is known as the Tatra-Fatra Belt comprising the Tatric-Fatric-Hronic nappe stack (Plašienka et al., 1997;

Plašienka, 2018). The nappe stack is preserved in several fault bounded mega-anticlinal horst structures called the “core mountains” emerging from the sedimentary fill of the surrounding Paleogene and Neogene basins. The uplift of the core mountains, based on zircon and apatite fission-track data (e.g. Burchart 1972; Kováč et al., 1994; Danišík et al., 2004; Králiková et al., 2016), started already in the Paleocene with the rapid acceleration since the Pliocene – Pleistocene.

Most of the published pre-Cenozoic paleomagnetic data from the Central Western Carpathians come from the Fatric Unit, mainly from the Polish part of the Tatry Mts.

(Kądziałko-Hofmokl and Kruczyk, 1987; Kruczyk et al., 1992; Grabowski, 1995; 2000;

2005). They are complemented by sporadic data from the Tatric and Hronic units in the Tatry Mts. (Grabowski 1997; 2000; Grabowski et al. 1999; Szaniawski et al., 2012) as well as from the Tatric and Fatric units of the remaining part of the “core mountains”: Nízke Tatry, Malá Fatra, Veľká Fatra (Kruczyk et al., 1992; Pruner et al., 1998; Szaniawski et al., 2020), Strážovské vrchy Mts. (Grabowski et al., 2009; Szaniawski et al., 2020) and Malé Karpaty Mts. (Grabowski et al., 2010). The majority of the reported paleomagnetic directions have

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been interpreted in terms of early pre- or syn-thrusting remagnetizations acquired during the Cretaceous Normal Super-Chron (Grabowski and Nemčok, 1999; Grabowski, 2000).

Exceptions are the Lower Triassic siliciclastic deposits resting directly upon the Tatric crystalline basement (Szaniawski et al., 2012; 2020) and Berriasian pelagic limestones of the Fatric Unit (Grabowski 2005; Grabowski and Pszczółkowski, 2006; Grabowski et al., 2009;

2010) where magnetization has been interpreted as primary. Unlike the Cenozoic paleomagnetic directions showing consistent 50-60° CCW rotations in all principal tectonic units of the Western Carpathians (see comprehensive review by Márton et al., 2016), the pre- Cenozoic paleodirections display a more complex pattern. The distribution of paleodeclinations for the Tatric and Fatric units (both primary and secondary) and their apparent agreement with nappe transport trajectories was originally taken as a proof for oroclinal bending of the Central Western Carpathians or alternatively interpreted in terms of radial thrusting (e.g. Kruczyk et al., 1992). However, recently documented primary magnetizations from the Tatric cover Unit (Szaniawski et al., 2012; 2020) show concordant paleodeclinations relative to the present north, consistent through a considerable part of the Central Western Carpathians, and therefore challenge the oroclinal bending model.

In the Hronic Unit, Late Paleozoic volcanic and sedimentary rocks were the targets of the very early paleomagnetic studies in the Western Carpathians (see review by Krs et al., 1982).

Results of these studies were among the first that have been interpreted in terms of large rotations within the Western Carpathians (Kotásek and Krs, 1965; Krs, 1966). The results were originally interpreted as CW vertical axis rotations. Later these paleomagnetic data were reinterpreted as CCW rotations (Márton et al., 1992; Krs et al., 1996), because some doubts had arisen about the sense of rotation in the light of the near-equatorial paleoposition of the studied rocks and the very similar angle of a Cenozoic CCW rotation documented for several areas in the Internal Western Carpathians (Márton et al., 2016 and references therein).

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The main aim of the present study was to obtain positive proofs for the sense and amount of rotations in the Hronic Unit. Thus, we conducted a modern paleomagnetic study on the Late Paleozoic volcanic and sedimentary rocks of the basal part of the Hronic Unit (black dots in Fig. 1), on one hand and a new systematic research on the Mesozoic, mostly Triassic sediments of the same unit (Fig. 1). Our research focused on the Nízke Tatry Mts., where the Late Paleozoic and Triassic rocks are well exposed and accessible for sampling. Additionally, we collected samples from the western sector of the Central Western Carpathians (Malé Karpaty, Považský Inovec and Strážovské vrchy Mts.) in order to have a control on possible relative rotations between different partial nappes of the Hronic Unit, which could be attributed to oroclinal bending.

2. Geological background

The structurally lowermost tectonic unit of the Central Western Carpatians is the Tatric Unit.

Its more frontal and distal elements, exposed in the Malé Karpaty, Považský Inovec and in the western part of the Malá Fatra Mts. (Fig. 1) are known as the Infra-Tatric Unit (Putiš, 1992;

Putiš et al., 2008; Plašienka, 2018). The Tatric and Infra-Tatric units are composed of the Variscan crystalline basement and its Late Paleozoic and Mesozoic para-autochthonous, mostly sedimentary cover. It is overthrust by the thin-skinned Fatric and the uppermost Hronic cover nappe units with Upper Paleozoic to Upper Cretaceous rock sequences. Based on deep reflexion seismic data (Tomek, 1993) the Tatric thrust-sheet is underlain by highly reflective horizons in middle crustal zones. These horizons were interpreted as remnants of the Vahic (South-Penninic) oceanic crust and basement-cover rocks of the Oravic ribbon continent (e.g. Plašienka 1995a; Bielik et al., 2004; Plašienka, 2012; Putiš et al., 2008, 2019) correlative to the Briançonnais units (Tomek, 1993) or Sub-Penninic units of the Western Alps (Schmidt et al., 2008). The Vahic Ocean is considered as the continuation of the Ligurian-Penninic oceanic tract to the Western Carpathians. The only fragments preserved on

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the present surface structure in the Western Carpathians interpreted as of the Vahic-Penninic origin are Upper Jurassic to Cretaceous eupelagic sediments and Senonian syn-orogenic clastic deposits of the Belice Unit in the Považský Inovec Mts. (Fig. 1) (Plašienka et al., 1994;

Plašienka, 1995b; Plašienka, 2012).

The basal part of the Hronic nappe system is represented by the uppermost Carboniferous- Permian volcano-sedimentary sequence called the Ipoltica Group (Vozárová and Vozár, 1981;

1988). The Ipoltica Group is characterized by the presence of voluminous basic to intermediate volcanic rocks with continental tholeiitic magmatic trend. They are related to a regional extensional tectonic regime, which led to the formation of a rift structure as a part of the continental margin or back-arc settings on the continental crust (Dostal et al., 2003; Vozár et al., 2015).

The Ipoltica Group comprises the uppermost Carboniferous-lowermost Permian Nižná Boca Fm. and the Permian Malužiná Fm. (Fig. 2). The former consists of a regressive lacustrine- deltaic succession including sandy shales, sandstones and conglomerates. The estimated maximum sedimentation age of the Nižná Boca Fm. is younger than 297 Ma, based on SIMS U-Pb detrital zircon dating (Vozárová et al., 2018). Sporadic doleritic sills and dykes, occurring in the upper part of the formation, are regarded as co-magmatic with the main Permian andesitic to basaltic volcanism of the younger Malužiná Fm. (Vozárová and Vozár, 1981; 1988).

The conformably overlying Malužiná Fm. consists of three fining-upward sedimentary megacycles (Vozárová and Vozár, 1981; 1988). These sedimentary cycles are composed of fluvial-lacustrine and alluvial red beds and locally also evaporites. The characteristic feature of the Malužiná Fm. is the extensive andesitic to basaltic volcanism, which was generated during two main eruption phases. The older one belongs to the 1st, the younger and more voluminous one to the 3rd megacycle (Vozár, 1977; 1997; Dostal et al., 2003; Vozár et al.,

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2015). The 2nd megacycle consists mainly of fluvial-alluvial clastic rocks with fining-upward trend. Small portions of effusive and volcaniclastic rocks occur at the base of the 2nd megacycle. Uranium mineralization from the middle to upper parts of the 2nd megacycle was dated to 263±11 Ma (Rojkovič, 1997). CHIME dating of detrital monazites from sandstones of the Malužiná Fm. provide the age 280-250 Ma, with the distinct peak at 255 Ma (Vozárová et al., 2014).

A different view on the division of the Malužiná Fm. was published by Novotný and Badár (1971). They suggested that the large volcanic complex is restricted to the Upper Permian.

These authors argued that the volcanic bodies, occurring in the lower part of the Malužiná Fm. represent, in fact, hypabyssal rocks genetically associated with the Upper Permian effusive complex.

The Ipoltica Group is directly overlain by Triassic sediments (Fig. 3). The Lower Triassic rocks are represented by siliciclastic deposits, like quartzitic sandstones followed by variegated shales, alternating with marlstones and sandy limestones in the upper part. The Triassic succession is comparatively thick and includes a wide range of carbonates, representing various parts of a shelf environment – from tidal flats and reef platforms up to pelagic intra-shelf basins, which were deposited in two basin and in two carbonate platform sedimentary realms (Havrila, 2011 and references therein). Carbonate sedimentation was interrupted by a fluvial event, at the Carnian-Norian boundary, depositing siliciclastic sediments that flattened basin-platform topography (Lunz Formation, Aubrecht et al., 2017;

Kohút et al., 2017). After this event, the unified shallow-water carbonate sedimentation was resumed during the Upper Triassic. The Jurassic and Lower Cretaceous condensed limestones are rare and the youngest sediments of the Hronic Unit are represented by Hauterivian distal turbidites.

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Structurally, the Hronic Unit is an internally complicated nappe system with numerous partial nappes and erosional remnants of the original coherent nappe body (Kováč and Havrila, 1998;

Havrila, 2011). In the rear (south-eastern parts in the present coordinates), the partial nappes comprise thicker sedimentary sequences involving Late Paleozoic of the Ipoltica Group and Mesozoic rocks. Towards the frontal parts, i.e. to the north and northwest, the partial nappes form a strongly imbricated system built up almost exclusively of carbonate sequences.

The first shortening events in the Hronic Unit is probably manifested by the Hauterivian turbidites. The final, in part gravity-driven emplacement together with the Fatric nappe system over the Tatric units is assumed to be very rapid during the Turonian (Plašienka, 2018). Tectonic transport directions (in present coordinates) vary from the NW-wards in the Nízke Tatry Mts., Chočské vrchy Mts. and Malá Fatra Mts. (Kováč and Havrila, 1998) to W- wards in the Považský Inovec Mts. (Pelech, 2015). Exceptional NE-wards tectonic directions were reported in the internal parts of the Central Western Carpathians, in the Sklené Teplice tectonic window (Hók et al., 2013) and in the SE part of the Tribeč Mts. (Ivanička et al., 1998).

3. Paleomagnetic sampling

Altogether, we collected samples at 24 Late Paleozoic and 20 Mesozoic localities (Figs. 1 to 4). Statistically acceptable directions were obtained for 20 Late Paleozoic (Table 1) and 16 Triassic localities (Table 2). The samples were drilled by using a portable water-cooled gasoline and an electric drill and oriented mainly by a magnetic compass or when the lithology or the situation required (e.g. closeness of a railway line) a sun compass was used.

Special care was taken to avoid slumps or weathered material. Localities that failed in retrieving palaeomagnetic directions are listed in Table 3.

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Volcanic and sedimentary rocks (red beds) of the Late Paleozoic Ipoltica Group were sampled mainly in the northern part of the Nízke Tatry Mts. in the Ipoltica Valley and parallel valleys (Figs. 1, 2, 4, 5A-C) where the most continuous sections of the Upper Paleozoic rocks are exposed. Additionally, basalts and tuffs were sampled in two quarries in the easternmost part of the Nízke Tatry Mts. and basalts in two quarries (two lava flows in each) in the Malé Karpaty Mts. (Figs. 1, 2, 4A). A doleritic dyke and uppermost Carboniferous to Lower Permian siltstones, close to the dyke, were also sampled at the type locality of the Nižná Boca Fm. in Nižná Boca village.

The Mesozoic rocks were sampled at geographically distributed localities in the Nízke Tatry, Malá Fatra, Strážovské vrchy, Považský Inovec and Malé Karpaty Mts. (Figs. 1, 3, 4). The sampled rocks include Lower Triassic variegated shales (Fig. 5D), Anisian Gutenstein limestones, Upper Anisian-Lower Carnian well-bedded cherty Reifling limestones (Fig. 5E), Lower Carnian Oponitz limestones, the uppermost Carnian-Norian Hauptdolomites and Dachstein Limestones (Fig. 3). Additionally, one locality of Upper Jurassic – Lower Cretaceous pelagic limestones (T19) in the Malé Karpaty Mts. was sampled. The age determination is based mainly on micropaleontology (see comprehensive review by Havrila, 2011).

4. Laboratory methods

The samples were cut to standard-size specimens by a water-cooled wheel-saw. Usually two specimens from a sample were obtained. The natural remanent magnetization (NRM) was measured by using JR-4, JR-5, JR-5A, JR-6A spinner magnetometers in Budapest, Banská Bystrica and Warsaw, respectively. The magnetic susceptibility and anisotropy of the low- field susceptibility was measured by a KLY-2 kappabridge (Agico, Czech Republic). Then, specimens were stepwise demagnetized by either thermal (Schonstedt TSD-1 thermal

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demagnetizer and a MMTD28 thermal demagnetizer Magnetic Measurements Ltd., the United Kingdom) or alternating field method (LDA-3A instrument, Agico, Czech Republic and Demag 0179 AF demagnetizer, Technical University, Budapest, Hungary). Magnetic susceptibility was monitored during thermal demagnetization.

Magnetic mineralogy experiments included Currie point measurements (using a CS-3 apparatus combined with a KLY-2 kappabridge, Agico, Czech Republic), acquisition of isothermal remanent magnetization (IRM) and thermal demagnetization of the three- component IRM (Lowrie, 1990). IRM was imparted on selected specimens by using a Molspin pulse magnetizer (maximum field 1 T).

5. Results

5.1. Permian red sediments and igneous rocks 5.1.1. Magnetic mineralogy

Magnetic minerals in these rocks were identified by monitoring the magnetic susceptibility during heating-cooling runs from room temperature up to 700°C. In some cases, the experiments started from liquid nitrogen temperature (e.g. Fig. 6, SMP160, 137).

In most of the basalts, and in intercalated tuffs (Fig. 6, SMP44), the magnetic mineral was identified as a slightly oxidized magnetite with Curie temperature a bit higher than 575°C.

Some exhibited the Verwey transition in the low-temperature part of the susceptibility curve (Fig. 6, SMP160), some well-defined Hopkinson peak at 540-580°C (Fig. 6, SMP36).

Exception is locality P18, where Curie point temperature around 680°C indicates haematite (Fig. 6, SMP9).

The red shales show presence of haematite, with Curie point around 680°C (Fig. 6, SMP131, 137). In addition, paramagnetic minerals (e.g. iron bearing silicate minerals) must be present

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in abundance. The paramagnetic hyperbola was especially well visible on the low-temperature part of the susceptibility curve for sample SMP137 (Fig. 6). The paramagnetic minerals seem to produce magnetite during heating (dramatically increased susceptibility on the cooling curves of SMP131 and SMP137 (Fig. 6).

5.1.2. Paleomagnetic results

The intensity of the NRM signal before demagnetization in the igneous rocks was very variable (1 x 10-3 – 5 x 10 A/m) and the magnetic susceptibility was between 245 and 49 229 x 10-6 SI. In the red sediments the NRM intensity was in the range of 9 x 10-5– 3 x 10-2 A/m, the susceptibility in the range of 37-283 x 10-6 SI.

Alternating Field (AF) demagnetization was ineffective for both types of rocks. Stepwise thermal method efficiently demagnetized the NRM signal (e.g. Fig. 7, specimens SMP28, 35, 46, 67, 135A, 156, 228). In cases, where the decay was not complete even at 680°C (Fig. 7, specimens SMP3, 77, 231) the tendency towards the origin of the Zijderveld diagram was clear. Thus, the experiments provided excellent material for principal component analysis (Kirschvink, 1980) and statistical evaluation on the locality level. The results are shown in Table 1. There was only one locality of red sediments where the directions of the NRM did not decay towards the origin, but moved along great circles (locality P3). In this case the McFadden and McElhinny (1988) method was used to determine the locality mean direction, but the result had to be excluded from tectonic interpretations due to larger than 16°

confidence circle. It is important to note that the locality mean directions, before tectonic corrections (Table 1), always depart significantly from the direction of the present local Earth´s magnetic field which is a sign of the long-term stability of the paleomagnetic signals.

5.2. Triassic sediments 5.2.1. Magnetic mineralogy

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Except for the Lower Triassic variegated siltstone (locality T1), the IRM acquisition curves showed the dominance of a magnetically soft magnetic mineral (Fig. 8). On the thermal demagnetization of the three component IRM, the variegated siltstone (Fig. 8, specimen SMP280B) clearly shows the dominance of the hard and medium hard components, which however, decay parallel to the soft component. The interesting aspect of the variegated siltstone in question is that a substantial part of the NRM survives even 700°C, pointing to hematite as the carrier of the NRM, while the IRM seems to be governed mainly by another magnetic mineral, possibly oxidized magnetite. In the other cases, the largest IRM component was soft. In specimens representing Anisian shallow-water carbonates (Fig. 8, SMP250A) and Anisian – Lower Carnian hemipelagic marly limestones (Fig. 8, SMP540) the soft component decayed well before the Curie point of magnetite, while the susceptibility re-measured after each heating step started to decrease dramatically as soon as the soft component was demagnetized. The IRM acquisition experiments repeated on the same specimens resulted in producing a mineral with much higher than the original intensity.

5.2.2. Paleomagnetic results

Initial values of the NRM were in the 1 x 10-3 and in the 1 x 10-2 A/m range. Magnetic susceptibilities varied from minus 6 to plus 309 x 10-6 SI. Thermal and AF demagnetizations, respectively, of sister specimens from pilot samples served as a basis for choosing the method for demagnetizing the rest of the samples from the respective localities. When the two methods produced similarly well-defined demagnetization curves, AF method was preferred to demagnetize the rest of the samples from a given locality in order to avoid mineralogical changes on heating. However, occasionally AF demagnetization was followed with a single heating step (Fig. 9, SMP 271 and 338A) in order to document that the results of the two methods define the same lines on the Zijderveld diagrams. The curves in Fig. 9 clearly show the presence of two components. The lower temperature component was easily removed and

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represents most probably the present day viscous remanent magnetization. The higher- temperature component decayed towards the origin. Exception is specimen SMP280A (Lower Triassic shale), where it was not possible to achieve the complete decay of NRM even at 675°C due to extremely high viscosity, which already started to disturb the measurements at 600°C.

The above results were evaluated by means of principal component analysis (see above) and the components heading towards the origin of the Zijderveld diagrams were entered into the statistical evaluation at the locality level. For locality T1, only a secondary component was identified, which was, however very well-defined for all the collected samples (Table 2, locality T1). The locality mean directions are very well-defined statistically and before tectonic corrections they differ from the present day direction of the Earth´s magnetic field (Dec=0, Inc=60°) at the sampling localities (Table 2).

6. Discussion

6.1. Discussion of the Permian paleomagnetic results

The results represent mostly volcanic rocks (lava flows, dykes, and in one case an intercalated tuff horizon) and red sediments. The positions of the lava flows were possible to measure directly from the attitude of intercalated tuffs or infer from the underlying and/or overlying sediments.

The paleomagnetic directions for the red sediments form two distinct groups (Fig. 10). Both are accompanied by those obtained for igneous rocks of Permian age. The larger group comprises all results from the Boca partial nappe from the Nízke Tatry Mts. and from the Malé Karpaty Mts. The remaining single igneous locality and two sedimentary localities from the Malužiná partial nappe form the other group. When calculating the overall mean paleomagnetic directions for the larger group, before and after tilt corrections, respectively,

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we observe some scatter, which is considerably reduced after omitting two directions (Table 1, localities P4, P9) using the method of Vandamme (1994). For the remaining 15 localities the tilt test is positive (Fig. 10) and the overall mean paleomagnetic direction is Dec=249.6°, Inc= -20.4°, k=22.9, α95=8.2. The result is interpreted in terms of about 70° CW net rotation with respect to the present north. It has to be noted, however, that the overwhelming dominance of the reversed polarity magnetizations (except locality P2, close to the bottom of the Ipoltica Valley section) fits better to ages older than 267 Ma for the source rocks (the end of the Kiaman Reverse-polarity Hyperchron is placed at ~ 267 Ma (Menning 1995; Ogg et al., 2016), but this is not critical from the viewpoint of the tectonic interpretation of the paleomagnetic results.

The above overall mean paleomagnetic direction is based on a robust set of data since they represent different lithologies and different carriers of the remanent magnetizations, either haematite (typical for red sediments, but also occurring at locality P18 in a lava flow) or magnetite, typical for the igneous rocks. Moreover, the sampling localities are geographically distributed and the paleomagnetic directions before tilt corrections are far from that of the present Earth´s magnetic field at the sampling area.

The smaller group consisting of localities P15, P16, P17 defines a paleomagnetic direction of Dec=187.4°, Inc=-21.4°, k=84, α95=13.5°, which is an apparently non-rotated paleomagnetic direction (Fig. 10). These localities belong to the Malužiná partial nappe which is structurally in higher position than the Boca partial nappe comprising the other localities from the Nízke Tatry Mts. (Fig. 4B). This result can be considered as the consequence of local tectonics, yet we cannot disregard another option. Namely, that the remanent magnetizations in the Malužiná partial nappe can be much younger than Permian, since before tilt corrections they are close to the reversed polarity counterpart of the direction of the present Earth´s magnetic

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field at the sampling area. In any case, at this stage of knowledge we have left them out from the regional tectonic interpretation.

6.2. Discussion of the Triassic paleomagnetic results

The statistically well-defined paleomagnetic directions for the Triassic sediments, mostly carbonates, except locality T1, were subjected to inclination-only as well as tilt tests (Fig. 11, 12). Three localities were not included in the tests. Two of them (T1 and T3) were omitted because of the obviously post-tilting age of the NRM (Fig. 11). For locality T1 the linear segment in the Zijderveld diagram is not decaying towards the origin (Fig. 9, SMP280A), thus the well-defined linear segment must represent secondary NRM. Locality T3 was affected by complicated syn-sedimentary and repeated post-sedimentary tectonic deformations. The third locality excluded from the tests is T9 as a consequence of the Vandamme cutoff (1994). For the remaining 13 localities the tests are positive (Figs.11, 12). Despite of this the primary origin of the magnetizations is not likely. The reason is that the sediments cover the time span from the Anisian to Norian (about 40 Ma) when numerous reversals of the geomagnetic field were detected (Ogg et al., 2016), while the Triassic localities exhibit exclusively normal polarities. Therefore, we interpret the results obtained for the Triassic rocks as the consequence of remagnetization during the Cretaceous Normal Super-Chron. Such interpretation of the new results for the Hronic Unit are in line with previous ones for the Mesozoic rocks of the Fatric and Tatric nappe units. According to Grabowski (2000) and Grabowski et al. (2009), the particular thrust slices were affected by remagnetization during the Cretaceous Normal Super-Chron at various stages of deformation, some in horizontal and some in tectonically inclined position.

A remarkable feature of the assemblage of the tilt corrected locality mean directions, obtained for Triassic rocks from the Hronic Unit is a quite tight cluster close to Dec=34°and Inc=54°.

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Although the population of the locality mean directions satisfy the criteria for Fisherian distribution, there are moderate (localities T6, T11-13) or considerable (locality T7) departures from the overall mean declination. As the Triassic results represent different partial nappes, distributed in W-E direction, it is logical to investigate the problem of possible bending after the acquisition of the remanence. As Fig. 13 documents such correlation is not in evidence, which prohibits an interpretation of the declination differences as a result of oroclinal bending or radial thrusting.

The duration of the Cretaceous Normal Super-Chron (124.5-83.5 Ma) leaves quite a long time period for remagnetization. This can be narrowed down to 90-80 Ma, based on numerous fission track and geochronological data. They record a thermal event at 90-80 Ma related to the burial of the crystalline basement due to overthrusting by the cover thin-skinned nappes followed by exhumation and collapse of the overthickened orogenic wedge during the Late Cretaceous to middle Eocene (e.g. for FT data see comprehensive review by Králiková et al., 2016; Putiš et al., 2008; 2019; Etzel et al., 2018).

The temperature in the Tatric-Infra-Tatric crystalline basement had to rise above 320°C, which is the upper limit for the zircon partial annealing zone (Tagami et al., 1998). At the same time the temperature did not exceed 350°C, because the Ar/Ar and Rb/Sr datings of the Tatric crystalline basement mostly record the Late Variscan 320-280 Ma ages (Janák and Onstott, 1993; Maluski et al., 1993; Janák 1994; Kráľ et al., 1997; 2013). There also exist isotope age data directly from the Hronic Unit representing the diagenetic age of tectonically induced burial due to thrusting. This was obtained with K-Ar method on bentonites forming thin layers of pyroclastic material within the Middle Triassic Reifling Fm. in the Tatry Mts.

(Sródon et al., 2006) and Považský Inovec Mts. (Wolska et al., 2002) which revealed similar ages around 90-80 Ma. The maximum paleotemperature in sedimentary sequences of the Hronic Unit was estimated to 160-270° C. Colour alteration indices (CAI) in the Hronic Unit

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are generally low, pointing only to diagenetic conditions. This elevated temperature is insufficient for thermal resetting (Grabowski et al. 1999; Gawlick et al., 2002), thus the remagnetization in the Triassic sediments is more likely of chemical than thermoviscous origin. The agents for remagnetization can be thrusting expelled orogenic fluids from the Tatric crystalline basement in the Fatric (Grabowski et al., 2009; Prokešová et al., 2012) as well as in the Hronic nappe units.

6.3. Paleotectonic implications

The Permian paleomagnetic inclinations for the Boca partial nappe of the Nízke Tatry Mts.

and for the Malé Karpaty Mts. suggest that the Hronic Unit was situated between stable Europe and Africa (Fig. 14). The paleolatitudes for the Triassic rocks fit perfectly the 90-80 Ma interval in a position close to the southern margin of stable Europe, thus reinforcing the acquisition of the remanences during thrusting. Compared to reference stable European and African declinations, a CCW rotation of about 60° taking place after 30 Ma must be taken into account for the Central Western Carpathians (see comprehensive review by Márton et al., 2016). This means that the Hronic Unit must have rotated relative to stable Europe about 90°

and to Africa about 110° in CW sense, after 90 Ma (Fig. 14 and supplementary material Table 1). The net vertical axis rotation between the Permian and the Late Cretaceous is about 36° in the CW sense (Table 4). This means about 21° relative to stable Europe and 50° to Africa in the CW sense. The timing of this older rotation is loosely controlled as it must have taken place after the Permian but before 90 Ma. The most likely time is between the Middle Triassic and Middle-Late Jurassic during the opening and closing of the Neo-Tethys Ocean, respectively (e.g. Gawlick and Missoni, 2019). Alternatively, it could be related to the prolonged extensional tectonic regime affecting substantial parts of the Central Western Carpathians during the Jurassic to Early Cretaceous (e.g. Plašienka, 2003; 2018).

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According to our new results, the Hronic Unit must have rotated again in the CW sense after 90-80 Ma. This rotation must have been very fast as the final nappe emplacement of the Fatric together with the Hronic Unit over the Tatric Unit took place in a narrow time range during the Turonian (Plašienka, 2018) with the possible continuation to the Santonian in the more external parts (Pelech et al., 2017; Hók et al., 2019). This interpretation is based on the following considerations. The youngest sediments preserved in the Tatric cover unit of the Central Western Carpathians range from the upper Cenomanian (Wolska et al., 2016) to the middle Turonian – Santonian (Pelech et al., 2017 and references therein). This provides the lower age limit for the thrusting of the Fatric and Hronic nappes. The upper age limit is controlled by the oldest coarse-grained deposits of the Gosau Group which are Coniacian in age, regarded as a new post-orogenic sedimentary cycle (Plašienka and Soták, 2015 and references therein). Therefore, the paleomagnetic results from the post-nappe successions of the Gosau Group are of crucial importance to constrain the timing of the CW rotations of the Central Western Carpathian nappes (Grabowski and Nemčok, 1999; Márton et al., 2016). The Gosau Group is represented by wedge-top, piggy-back basins developed on top of the accretionary wedge of the upper plate tip facing the trench/fore-deep depozones of the subducting South-Penninic oceanic or subcontinental crust (for comprehensive review see Plašienka and Soták, 2015; Putiš et al., 2019). The evolution of the Gosau Group basins was largely controlled by the dynamics of the underlying wedge composed of the frontal elements of the Fatric-Hronic nappe systems. The erosional remnants of the originally much more extended Gosau basins in the Central Western Carpathians have been preserved mainly in the northern part of the Malé Karpaty Mts., in the Middle Váh Valley and in the Žilina-Rajec Basin (Plašienka and Soták, 2015). Some other occurrences have been preserved in a zone rimming the southern side of the Pieniny Klippen Belt with complex stratigraphic relations due to the Late Eocene to Miocene tectonics (Fig. 1, 15). So far, only few paleomagnetic

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directions of pre-tilting age were published for the Campanian to middle Eocene sediments of the Gosau Group showing large 59-110° CCW vertical axis rotations (Márton et al., 1992;

2013; Túnyi and Márton, 1996). The most reliable result comes from the Campanian red marls in the Malé Karpaty Mts. (Fig. 15, item 1 in Table 1 in Márton et al., 2013) showing about 60° CCW vertical axis rotation, which is in line with evidences for the regional Miocene CCW rotation observed for the External Western Carpathian Flysch Belt, Pieniny Klippen Belt and the Central Carpathian Paleogene Basin (Márton et al., 2016 and references therein). Accordingly, the CW rotations in the Central Western Carpathian cover nappe units should have ceased before the Campanian. Considering the well-documented about 60° CCW general rotation (Márton et al., 2009; 2016) observed for the Late Eocene to Oligocene sediments of the Central Carpathian Paleogene Basin (Fig. 15), which represents the younger overstep sequence with distinctive transgressive position above the Gosau Group in the Žilina-Rajec Basin (Soták et al., 2017; 2019), or more to the east, above various erosional levels of the Central Western Carpathian nappe structure (e.g. Soták et al., 2001) the total pre- Senonian CW rotation inferred is about 94°.

The question is if the post-Cenomanian and pre-Senonian CW vertical axis rotation was entirely or partly due to the emplacement of the Hronic Unit above the deeper nappe units, or the whole assemblage of the Central Western Carpathian nappe pile was participating in it.

The earlier published (see review by Márton et al., 2016) pre-Cenozoic paleomagnetic results from the Central Western Carpathian units (Fig. 15) were obtained at very different times using different field and laboratory methods. Moreover, they produced mostly sporadic data, which are difficult to consider as constraints for tectonic models. Nevertheless, some have been interpreted as a result of oroclinal bending or radial thrusting (e.g. Kruczyk et al., 1992;

Grabowski and Nemčok 1999; Grabowski et al., 2010). More recently paleomagnetic results were reported from Lower Triassic red beds resting directly upon the Tatric crystalline

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basement (Szaniawski et al., 2012; 2020), which show virtually no rotation in relation to the present north (small black arrows in Fig. 15). Unlike our Permian results, these directions are conspicuously close to the present day Earth´s field direction at the sampling localities before tectonic corrections, yet are interpreted as primary due to positive tilt test. A remarkable feature of these results is that they exhibit consistent paleomagnetic declinations throughout the substantial part of the Central Western Carpathians. Thus, similarly to our present findings, they do not support the oroclinal bending model of the Central Western Carpathians.

On the merit of the positive tilt test, Szaniawski et al., (2012; 2020) postulated a post-Lower Triassic moderate CCW rotation with respect to the APWP for stable Europe. These authors assume that this CCW rotation took place during Late Cretaceous thrusting. In the view of our results from the Hronic Unit, this means a considerable relative rotation between the Tatric and Hronic units during the nappe emplacements. Proving or rejecting such model requires further paleomagnetic investigations.

Conclusions

The presented paleomagnetic results from the Late Paleozoic and Triassic rocks of the Hronic nappe units demonstrate that:

1) The Permian overall mean paleomagnetic direction is based on a robust set of data since it relies on locality mean directions, which are geographically distributed, represent different lithologies, and different carriers of the remanent magnetizations. Moreover, the paleomagnetic directions before tilt corrections are far from that of the present Earth´s magnetic field at the sampling area pointing to a long-term stability of the paleomagnetic signal. Tilt test constraining the age of the magnetization is positive. The paleolatitude calculated from the overall mean inclination points to a paleoposition of the studied area close to the European platform during the Permian.

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2) The paleomagnetic directions of the Anisian – Norian carbonate sediments are significantly different from that of the present Earth´s magnetic field in the sampling area (evidence for long term stability). Most of the paleomagnetic directions obtained for geographically distributed localities pass inclination-only and tilt tests with the positive result. Nevertheless, the primary origin of the ChRM was excluded because of solely normal polarities and the paleolatitude fitting the 90-80 Ma interval in a position close to stable Europe.

3) The overall mean paleodeclination for the Triassic sediments with Late Cretaceous remagnetizations show about 34° CW rotation relative to the present north, which considering the 60° CCW Miocene rotation of the Central Western Carpathians means about 94° CW vertical axis rotation. This rotation must have taken place during Turonian – Santonian and can be connected to thrusting of the Hronic Unit over the structurally lower nappe units and/or the simultaneous rotation of the whole nappe stack connected to the subduction of the South-Penninic oceanic crust below the Central Western Carpathians accretionary wedge.

4) The older CW rotation affecting the Hronic Unit was about 36°. We interpret it as a vertical axis block rotation connected to major tectonic events in the Neo-Tethys.

5) Our data set does not support oroclinal bending during or after nappe emplacement.

6) Our future research will concentrate on the nappe units below the Hronic Unit, in order to solve problems, like possible simultaneous rotations of the Tatric-Fatric-Hronic nappe stack and the problem of the correct model in which some earlier observed differences in locality mean declinations can be interpreted.

Acknowledgements. This study was financially supported by the National Development and Innovation Office of Hungary (project K128625), the Slovak Research and Development

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Agency (projects APVV-0212-12, APVV-17-0170) and VEGA Agency (projects 2/0028/17, 1/0151/19). Constructive reviews by Miguel Garcés and an anonymous reviewer are gratefully acknowledged. We thank Tadeusz Sztyrak for technical assistance in the field and laboratory. Thanks to Tomáš Flajs (National Park Malá Fatra) for working permissions and guidance during field work at localities in the Malá Fatra Mts.

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Table 1

Locality Litostratigraphy Coordinates n/no D° I° K α95° DC° IC° k α95° Dip Lat° Lon° δp° δm° B95° plat°

NT

P1 Ipoltica 2

SMP128-137 Malužiná Fm. red shale 1st megacycle Lower Permian

48°58’17.1”

19°58’54.9” 10/10 249 -23 230.2 3.2 241 -12.2 230.2 3.2 358/27 23.5 128.4 3.2 1.6 2.3 6.2

P2 Ipoltica 3

SMP138-147 Malužiná Fm. basaltic andesite/basalt 1st megacycle Lower Permian

48°58’16.0”

19°58’54.9” 10/10 97.1 12.3 72.3 5.7 90.4 15.1 72.3 5.7 358/27 5.5 104.6 5.9 3.0 4.2 7.7

P4a Ipoltica 5a SMP180-190

Malužiná Fm. basaltic andesite/basalt 1st megacycle Lower Permian

48°58’33.8”

19°58’41.0” 9/11 45.0 -22.0 37.7 8.5 73.1 -42.1 37.7 8.5 353/46

P5 Ipoltica 7 SMP213-218

Malužiná Fm. red siltstone 1st megacycle Lower Permian

48°58’50.6”

19°58’30.4” 5/6 268.4 -10.9 52.7 10.6 258.1 -12.8 52.7 10.6 351/46 12.7 114.7 10.8 5.5 7.7 6.5 P6 Ipoltica 4

SMP148-160

Malužiná Fm. basaltic andesite/basalt 3rd megacycle Upper Permian

48°59’42.9”

19°57’42.2” 12/13 250.1 -17.4 42.7 6.7 242.2 -10.2 42.7 6.7 348/32 22.1 128.2 6.8 3.5 4.8 5.3 P7 Ipoltica 1

SMP100-108

Malužiná Fm. basaltic andesite/basalt 3rd megacycle Upper Permian

49°00’04.6”

19°57’16.0” 9/9 273.5 -14.2 279.9 3.1 267 -10.0 279.9 3.1 8/30 5.8 108.9 3.1 1.6 2.2 5.0 P8 Nižný Chmelinec

SMP259-266

Malužiná Fm. basaltic andesite/basalt 3rd megacycle Upper Permian

48°58’35.7”

19°54’04.0” 5/8 261.4 -12.3 90.7 8.1 248.2 -27.6 90.7 8.1 322/38 25.3 116.6 8.8 4.8 6.5 14.6 P9 Svarinka 4

SMP233-240

Malužiná Fm. basaltic andesite/basalt 3rd megacycle Upper Permian

48°58’31.5”

19°52’06.9” 8/8 241.3 13.6 54.9 7.5 256.6 +22.7 54.9 7.5 350/45

P10 Svarinka 2-3 SMP228-232

Malužiná Fm. red shale/siltstone +

basaltic andesite/basalt 3rd megacycle Upper Permian

48°50’41.2”

19°51’53.1” 5/5 250.3 -17.9 138.1 6.5 241.4 -10.3 138.1 6.5 348/35 22.4 128.8 6.6 3.4 4.7 5.2

P11 Kvetnica 1 SMP30-39 SMP47-50

Malužiná Fm. basaltic andesite/basalt 3rd megacycle Upper Permian

49°00’38.8”

20°17’14.2” 9/14 249.2 -41.2 62.3 6.6 247.8 -15.3 62.3 6.6 63/26 20.4 122.2 6.8 3.5 4.9 7.8 P12 Kvetnica 2

SMP40-46 Malužiná Fm. tuffs 3rd megacycle Upper Permian

49°00’38.8”

20°17’14.2” 7/7 266.3 -50.5 165.2 4.7 259.2 -25.9 165.2 4.7 63/26 17.3 109.2 5.1 2.8 3.7 13.6 P13 Nižná Boca 1

SM2418-2425 Nižná Boca Fm.

doleritic dyke Upper Permian?

48°56’59.5”

19°46’00.3” 8/8 282.6 -38.0 80.9 6.2 220.3 -40.2 80.9 6.2 340/65 49.0 134.5 7.5 4.5 5.8 22.9

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