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Ŕ periodica polytechnica

Chemical Engineering 57/1–2 (2013) 3–9 doi: 10.3311/PPch.2163 http://periodicapolytechnica.org/ch

Creative Commons Attribution RESEARCH ARTICLE

Modelling of Heat Transfer Processes with Compartment/Population Balance Model

Zoltán Süle/Béla G. Lakatos/Csaba Mihálykó/Éva Orbán-Mihálykó

Received 2012-05-15, accepted 2013-01-09

Abstract

A compartment/population balance model is presented for de- scribing heat transfer in gas-solid fluidized bed heat exchangers, modelling the particle-particle and particle-surface heat trans- fers by collisions. The results of numerical experimentation, ob- tained by means of a second order moment equation model indi- cate that the model can be used efficiently for analysing fluidized bed heat exchangers recovering heat either by direct particle- fluid heat exchange or indirect tube-in-bed operation mode. The population balance model is validated with physically measured data taken from the literature [6].

Keywords

heat transfer ·fluidized bed heat exchanger · compartment model·population balance model·simulation

Acknowledgement

This work was supported by the Hungarian Scientific Re- search Fund under Grant K77955 which is gratefully acknowl- edged. The financial support of the TAMOP-4.2.1/B-09/1/KONV- 2010-0003 project is also acknowledged.

This work was presented at the Conference of Chemical En- gineering, Veszprém, 2012.

Zoltán Süle

Department of Computer Science and Systems Technology, University of Pan- nonia, Veszprém, Egyetem u. 10, Veszprém, H-8200, Hungary

Béla G. Lakatos

Department of Process Engineering, University of Pannonia, Veszprém, Egyetem u. 10, Veszprém, H-8200, Hungary

e-mail: lakatos@fmt.uni-pannon.hu

Csaba Mihálykó Éva Orbán-Mihálykó

Department of Mathematics, University of Pannonia, Veszprém, Egyetem u. 10, Veszprém, H-8200, Hungary

Introduction

Fluidized bed heat exchangers, widely used in the metallurgi- cal and process industries are important tools for recovering heat from hot solid particles [1]–[7]. In these systems heat exchange with the wall usually is modelled by means of suspension-wall heat transfer coefficients which, in principle, are aggregates of two transfer components: gas-wall and particle-wall heat trans- fers. However, because of intensive motion of particles, the particle-wall, and also the particle-particle heat transfers are col- lision induced processes thus it seems to be significant to model these processes by themselves. Using such modelling approach the gas-wall and particle-wall components can be separated that allows understanding the transfer mechanisms involved.

For modelling and simulation of collision heat transfer pro- cesses in gas-solid systems, an Eulerian-Lagrangian approach, with Lagrangian tracking for the particle phase [8]–[11], and a population balance approach [12]–[16] have been applied. The population balance model, involving both the collision particle- particle and particle-wall heat transfers, was extended by Süle et al. [17, 18] for describing the spatial distributions of temper- atures in deep or long fluidized beds developing a compartment model.

The aim of the paper is to extend the compartment population balance model to describe the heat transfer processes in fluidized bed heat exchangers in which the heat of hot solid particles is used to heat water flowing in tubes immersed in the bed. We ap- ply a two-phase model of gas-solid fluidisation assuming that no bubbles are formed in the bed. The particle-particle and particle- tube heat transfers are modelled by collisions, while the gas- particle, gas-tube and tube-water heat transfers are described as continuous processes using linear driving forces.

Physical model

Consider a shallow fluidized bed in which particles trans- ported horizontally through the bed are fluidized by cross-flow air fed into the system in equally distributed gas streams along the bed. Cold water to be heated is flowing inside a tube im- mersed in the bed. The fluidizing air induces intensive particle- particle and particle-tube collisions, and heat transfer between the gas, particles and water through the wall of the tube.

(2)

The assumptions concerning the system are as follows: 1) The particles are of constant size and are not changed during the process; 2) The system is operated under steady state hydrody- namic conditions, and the influence of thermal changes on the hydrodynamics is negligible; 3) There is no heat source inside the particles. 4) The heat transfer by radiation is negligible.

The structure of the compartments, as well as of the mass and heat flows of the system is shown in Figure 1. In this system the following mass transport processes are distinguished.

Fig. 1. The scheme of the system

(1) Volumetric cross-flow qgof the fluidizing gas through the ideally mixed cells between which some cross-mixing occurs.

The temperature of gas in the kth cell is denoted by Tg,k, and there occurs continuous heat transfer between the gas and par- ticles, and the gas and wall, characterised by the heat transfer coefficients hgp, and hgw, respectively.

(2) Dispersed plug flow of particles through the bed modelled by the cells-in-series with back-flow model. Here, nk(Tp,t) de- note the population density function for the kth cell by means of which nk(Tp,t)dTpprovides the number of particles from the interval (Tp,Tp +dTp) in a unit volume of the cell at time t.

Inter-particle heat transfer occurs by collisions, and is described by the random variable Ωpp with probability density function fpp, while the particle-wall heat transfer also occurs by colli- sions that are characterised by the random variableΩpw with probability density function fpw.

(3) The heat in the wall of the tube is transported by conduc- tion, and the continuous wall-liquid heat transfer is characterised by the heat transfer coefficient hwl.

(4) The volumetric flow qlof water inside the tube is modelled also by the cells-in-series with back-flow model. It is assumed to be counter-current one with respect to the volumetric flow of particles.

In the present model, as it is illustrated in Figure 1, all com- partments (cells) describing the shallow fluidized bed are of the same volume Vk, while, for the sake of computational simplicity, the number of discrete elements of the tube wall and of the cells of model of flowing liquid, although their volumes are quiet dif- ferent, are the same as that of the bed compartments along the axial direction x.

Mathematical model

Under these conditions, the mathematical model of the heat transfer processes of the system is formed by a mixed set of par- tial integral-differential, partial differential and ordinary differ- ential equations. The population balance equation, which gov- erns the variation of the population density function of particle population in the individual cells, is a partial integral differential equation and can be written as

∂nk(Tp,t)

∂t +agphgp cpmp

∂h

Tg;k(t)Tp

nk(Tp,t)i

∂Tp

(1)

=

1+SkRp

qp

Vk

nk−1(Tp,t)+Sk+1Rpqp Vk

nk+1(Tp,t)

1+ZkRp

qp

Vk

nk(Tp,t)Spwnk(Tp,t)Sppnk(Tp,t)

+Spw 1

Z

0

nk

TppwωpwTw;k

1−pwωpw ,t

! fpwpw) 1−pwωpwpw

+2Spp

M0;k

Tp max

Z

Tp min 1

Z

0

fpppp) ωpp nk

2(Tp−τ) ωpp +τ,t

!

nk(τ,t) dωpp

where k=1,2, ...,K, t>0, the variables ωpp:=1−exp

"−2hppappθpp

mpcp

# and

ωpw:=1−exp







−hpwapwθpw

mpcp+mwcw mpcpmwcw







(2)

represent the realizations of the random variablesΩppandΩpw

which express, in principle, the efficiencies of the collision particle-particle and particle-tube wall heat transfers [16]. Here, agp, app and apwdenote, respectively, the gas-particle, particle- particle and particle-wall contact area, θpp andθpw denote the corresponding contact times and Rpstands for the back-flow ra- tio of particles. Parameter pw represents the ratio of thermal capacities of particles and the wall, while parameters Sland Zl

were introduced for characterising the compartmental structure of the system in a compact form where: S1 =0, SK =1, Z1= ZK=1, Sl=1, Zl=2, l=2, . . . , K−1.

The first term on the left hand side of Eq.(1) denotes the rate of accumulation of particles having temperature (Tp,Tp+dTp), while the second term describes the change of the number of particles with temperature (Tp,Tp+dTp) due to the gas-particle heat transfer. The first three terms on the right hand side rep- resent the input and output rates of particles from and to the

Per. Pol. Chem. Eng.

4 Zoltán Süle/Béla G. Lakatos/Csaba Mihálykó/Éva Orbán-Mihálykó

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neighbouring cells, as well as to and from the system, the next two terms describe the variation of the population density func- tion due to the collision particle-tube wall heat transfer, while the last two terms describe the change of nk(Tp,t) because of the collision heat exchange between the particles.

The heat balance equations for the temperature of fluidizing gas in the individual cells become

dTg,1(t) dt = qg,1

ε1V1Tg,1,in(t)qg,1

ε1V1Tg,1(t)2Rgq

ε1V1 Tg,2(t) (3)

−ε1(1+Rg)q

ε1V1 Tg,1(t)agwhgw

cgρg

x1

Z

0

Tg,1(t)Tw(x,t) dx

agphgp

cgρg Tp max

Z

Tp min

Tg,1(t)Tp

n1(Tp,t) dTp, t>0

dTg,k(t) dt = qg,k

εkVkTg,k,in(t)qg,k

εkVkTg,k(t) (4)

k−1(1+Rg)q εkVk

Tg,k−1(t)k+1Rgq

εkVk

Tg,k+1(t)−εk(1+2Rg)q εkVk

Tg,k(t)

agwhgw

cgρg xk

Z

xk−1

Tg,k(t)Tw(x,t) dx

agphgp

cgρg Tp max

Z

Tp min

Tg,k(t)Tp

nk(Tp,t) dTp

k=2, ...,K−1, t>0

dTg,K(t) dt = qg,K

εKVKTg,K,in(t)qg,K

εKVKTg,K(t) (5)

K−1(1+Rg)q εKVK

Tg,K−1(t)−εK(1+Rg)q εKVK

Tg,K(t)

agwhgw

cgρg xK

Z

xK−1

Tg,K(t)Tw(x,t) dx

agphgp

cgρg Tp max

Z

Tp min

Tg,K(t)Tp

nK(Tp,t) dTp, t>0

whereεk denotes the bed voidage in the kth cell, q stands for the volumetric gas flow between the cells causing some cross- mixing between the neighbour cells, Rg denotes the back-flow ratio for gas, and coefficient hgw represents the gas-wall heat transfer rate. Since the gas is assumed to be fed into the system equally distributed along the axial coordinate x we can write εk=constant for all k=1,2. . .K.

Heat in the wall of tube is transported with conduction hence the differential equation describing the temperature of the wall

can be written in the form

∂Tw(x,t)

∂t = kw

ρwcw

2Tw(x,t)

∂x2 +agwhgw

cwρw

Tg,k(t)Tw(x,t) (6) +awlhwl

cwρw

Tw(x,t)Tl,k(t)

+Spw

T p max

Z

Tp min

1

Z

0

ppωpw

TpTw(x,t) nk

Tp,t

fpwpw) dωpwdTp,

t>0, x[(k−1)∆x,kx], k=1,2, ...,K, subject to the boundary conditions

∂Tw(x,t)

∂x x=0

=0 and ∂Tw(x,t)

∂x x=X

=0. (7)

In Eq.(6), kwdenotes the thermal conductivity of the wall and the coefficient hwl stands for the wall-liquid heat transfer rate.

Parameters agwand awldenote the surface area of gas-wall and wall-liquid heat transfers in a unit length of tube.

Finally, the set of differential equations for the temperature of liquid phase compartments is written as

dTl,k(t)

dt = Sk−1Rlql

Vl,k Tl,k−1(t) (8)

+(1+Sk+1Rl) ql

Vl,k Tl,k+1(t)−(1+ZkRl)ql

Vl,k Tl,k(t) +awlhwl

clρl

xk

Z

xk−1

Tw(x,t)Tl,k(t)dx, k=1,2, ...,K, t>0

where the values of the S and Z parameters, characterising the structure of the system are: S0 =0, SK =0, SK+1=0,Sl =1, Z1=ZK =1, Zl=2, l=1, ..., K−1. The additional boundary conditions to Eqs (1)-(8) can be written as

n0(Tp,t)=nin(Tp,t) and Tl,K+1=Tl,in (9) which, naturally, should be completed with the appropriate ini- tial conditions.

Solution of the model equations

The mixed set of differential equations (1)–(9) was solved by reducing the population balance equation (1) and the heat con- duction equation (6) into two sets of ordinary differential equa- tions applying, respectively, a moment equation reduction and a finite difference discretization, obtaining in this way together with the gas phase equations (3)–(5) and liquid phase equation (8) a closed set of ordinary differential equations.

The moments and normalized moments of the temperature of particle population are defined as

MI;k(t)=

Tp max

Z

Tp min

TpInk(Tp,t)dTp,

mI;k(t)= MI;k(t)

M0;k(t), I=0,1,2, . . ., k=1, . . . ,K (10)

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which are useful for the basic characterisation of the temperature distribution of particles. The zero order moments M0;kprovide the total numbers of particles in a unit volume of cells by means of which the solids concentrations can also be computed, while the mean temperature of particles in the kthcell is expressed by m1;k(t). Completing the zero and first order moments M0;k and M1;k with the second order one M2;k, the variance of tempera- ture, defined as

σ2k= M2;k

M0;k

M1;k

M0;k

!2

(11) can also be computed.

The infinite hierarchy of the moment equations generated by the population balance equation (1) has the form

dMI;k(t) dt =IKgp

hMI−1;k(t)Tf ;k(t)MI;k(t)i +Spp





 1 M0;k(t)

I

X

i=0

Mi;k(t)MI−i;k(t)b(pp)i,IMI;k(t)







+Spwp1

"

−MI;k(t)+

I

X

i=0

I i

! b(pw)i

i

X

j=0

i j

!

(−1)i−jTw;kj MI−j;k(t)

#

+(1+SkRp)qp

V MI;k−1(t) +Rpqp

V MI;k+1(t)−(1+ZkRp)qp

V MI;k,

k=1,2, ...,K, I=0,1, ..., t>0 (12) where

b(pp)i,I =

1

Z

0

I i

pp

2 i

1−ωpp

2 I−i

fpppp) dωpp and

b(pw)i =

1

Z

0

ωipwfpwpw) dωpw. (13)

Since the infinite set of moment equations can be closed at any order, the second order moment equation reduction can be com- puted exactly by solving the equations for the first three lead- ing moments. This reduction is obtained by using the following equations. The total number of particles in the kthcell:

dM0;k(t)

dt = (1+SkRp)qp

V M0;in(t) +Rpqp

V M0;k+1(t)−(1+ZkRp)qp

V M0;k(t),

k=1,2, ...,K (14)

The first order moment of the particulate phase in the kthcell:

dM1;k(t)

dt = agphgp

cgρg

M0;k(t)Tg;k(t)M1;k(t) +Spwpwb(pw)1 M0;k(t)Tw;k(t)M1;k(t) +(1+SkRp)qp

V M1;in(t) +Rpqp

V M1;k+1(t)−(1+ZkRp)qp

V M1;k(t),

k=1,2, ...,K (15)

The variance of temperature of the particulate phase in the kth cell:

2k(t) dt =−

"

2agphgp

cgρg

+Sppb(pp)1,2 +Spwpw

2b(pw)1pwb(pw)2 + qp

V M0;k(t)

RpM0;k+1(t)#

·σ2k(t) +qp

V

(1+SkRp)M0,in(t) M0;k(t)

σ2in(t)−σ2k(t)

(16) +Spwb(pw)2 p2w M1;k(t)

M0;k(t)Tw;k(t)

!2

+qp(1+SkRp)M0;in(t) V M0;k(t)

M1;in(t)

M0;in(t)M1;k(t) M0;k(t)

!2

+RpqpM0;k+1(t) V M0;k(t) σ2k+1(t) +RpqpM0;k+1(t)

V M0;k(t)

M1;k+1(t)

M0;k+1(t)M1;k(t) M0;k(t)

!2

, k=1,2, ...,K

The set of equations provided with finite difference discretiza- tion of the heat conduction equation (6) for the wall has the form:

dTw,1(t) dt = DT

x2 Tw,2(t)Tw,1(t) (17) +agwhgw

cwρw

Tg,1(t)Tw,1(t)

awlhwl

cwρw

Tw,1(t)Tl,1(t)

Spw Tp max

Z

Tp min

1

Z

0

pp

Tw,1(t)Tp

n1

Tp,t

ωpwfpwpw)dωpwdTp,

t>0 dTw,k(t)

dt = DT

x2 Tw,k+1(t)2Tw,k(t)+Tw,k−1(t) (18) +agwhgw

cwρw

Tg,k(t)Tw,k(t)

awlhwl cwρw

Tw,k(t)Tl,k(t)

Spw Tp max

Z

Tp min 1

Z

0

pp

Tw,k(t)Tp

nk

Tp,t

ωpwfpwpw)dωpwdTp

k=2,3, ...,K−1, t>0

dTw,K(t) dt = DT

x2 Tw,K(t)Tw,K−1(t) (19)

+agwhgw

cwρw

Tg,K(t)Tw,K(t)

awlhwl

cwρw

Tw,K(t)Tl,K(t)

Spw

Tp max

Z

Tp min

1

Z

0

pp

Tw,K(t)Tp nK

Tp,t

ωpwfpwpw)dωpwdTp,

t>0

so that the integrals of variable x in Eqs (3)-(5) for the fluidiz- ing gas and Eqs (8) for the liquid flowing in the tube are also rewritten for the discrete values Tw,k(t), k=1,2, . . .,K.

Per. Pol. Chem. Eng.

6 Zoltán Süle/Béla G. Lakatos/Csaba Mihálykó/Éva Orbán-Mihálykó

(5)

Figure 3: Transients of the mean temperature of particles and the temperature of air in the cells

!"#$ !"#! !"" !"! !"$ !"%

!"

!$

!&

!'

!(

$"

$$

$&

$'

$(

%"

Figure 4: Transients of the temperature of water flowing in the tube

!" oC

#" s 1st cell

9th cell

1st cell 9th cell

$%&'(#)

!(&'(#)

#" s

!" oC

9th cell

1st cell

!"#$%&"''(!"#$%#&'!()*+,

*%-./0-.%-,,1$2-..-*Ę&31,

!"#$%&"''(!"#$%#&'!()*+,

*%-./0-.%-,,1$2-..-*Ę&31, Fig. 2. Transients of the mean temperature of particles and the temperature

of air in the cells

Simulation results and discussion of the models A computer program was developed in MATLAB environ- ment for solving the set of ordinary differential equations (3)–

(5), (8) and (14)-(19) taking into account all modifications of the integral terms. The program can generate and handle a com- partment/moment equations model consisted of cells of arbitrary number, and the resulted set of ordinary differential equations is solved by means of an ode-solver of MATLAB. The transient and steady state simulation results presented here were obtained for 9 cells using the basic constitutive expressions presented in detail in [16].

Figure 5 shows the variation of the variance of temperature of particle population as a function of time. The temperature of particles at the input was homogeneous but it became strongly distributed during the transient process showing rather large variances. The simulation results have shown that the gas-particle and particle-wall heat transfers induce inhomogeneities of the temperature of particles but the particle-particle collision heat transfer shows a strong indirect effect.

Conclusions

The compartment/population balance model, developed for describing heat transfer processes in gas-solid fluidized bed heat exchangers, and modelling the particle-particle and particle-surface heat transfer processes by collisions can be used efficiently for analysing the fluidized bed heat exchangers recovering heat from hot particles and heating some liquid flowing in a tube immersed in the bed. The model describes the temperature distribution of the particle population, and allows separating the effects of the fluidizing gas-immersed surface and particle-immersed surface heat transfers. The second order moment equation reduction, generated from the population balance equation has proved to be an efficient tool for studying the behaviour of heat exchangers.

! " # $ % & ' ( )

"**

#**

$**

%**

&**

'**

+

+

,-./0+.121 ,/1345/.+.121+6&7

Figure 2: The results of the compartment/population balance model compared with the experimental data by Pécora and Parise [6] when the input temperatures of

particles were 708 oC

Cell No.

!, °"

!"#$%&"''(!"#$%#&'!()*+,

*%-./0-.%-,,1$2-..-*Ę&31,

Fig. 3. The results of the compartment/population balance model compared with the experimental data by Pécora and Parise [6] when the input temperatures of particles were 708 °C

The predictions of the second order moment equation reduc- tion model were validated using the experimental data measured in a laboratory shallow fluidized bed heat exchanger published by Pécora and Parise [6]. Figure 3 presents the bed tempera- ture profiles for 9 cells comparing the model data with the mea- sured ones [6] when the input temperatures of particles were 708 °C, respectively. The parameters were fitted to the mea- sured values using a least squares method. The results in both

Figure 3: Transients of the mean temperature of particles and the temperature of air in the cells

!"#$ !"#! !"" !"! !"$ !"%

!"

!$

!&

!'

!(

$"

$$

$&

$'

$(

%"

Figure 4: Transients of the temperature of water flowing in the tube

!" oC

#" s 1st cell

9th cell

1st cell 9th cell

$%&'(#)

!(&'(#)

#" s

!" oC

9th cell

1st cell

!"#$%&"''(!"#$%#&'!()*+,

*%-./0-.%-,,1$2-..-*Ę&31,

!"#$%&"''(!"#$%#&'!()*+,

*%-./0-.%-,,1$2-..-*Ę&31,

Fig. 4.Transients of the temperature of water flowing in the tube

cases show rather good correspondence but it has to be taken only as preliminary ones since the heat transfer coefficients have been compared yet. Figure 2 presents the transients of the mean temperature of particles and the temperature of the fluidizing air in the cells along the heat exchanger. It is seen that in steady state these temperatures become almost equal and the heat of hot particles becomes transferred to the cold water. Under such conditions, the temperature of gas passes a maximum in each cell but delayed to each other in time. Similar maxima can be observed also in the transient processes of the wall, and in the temperature of liquid, as it is presented in Figure 4, heated by the hot particles through the tube wall.

Figure 5 shows the variation of the variance of temperature of particle population as a function of time. The tempera- ture of particles at the input was homogeneous but it became strongly distributed during the transient process showing rather large variances. The simulation results have shown that the gas- particle and particle-wall heat transfers induce inhomogeneities of the temperature of particles but the particle-particle collision heat transfer shows a strong indirect effect.

Figure 5: Transients of the variance of temperature of particle population Symbols

!

"! – surface area, m2

#! – specific heat, J kg-1 K-1

$! %! diameter!&'(

)! – width of the bed, m

*! – diameter of the tube, m

*+! – thermal diffusivity,

! ! *+ -,/U,#,, m2 s-1 .! – probability density function / – heat transfer coefficient,

W m-2 K-1

- – thermal conductivity, W m-1 K-1

0! – number of cells

1! – length of fluidized bed (') '! – mass, kg

2-!-3/ order moment of particle temperature

'-! – normalised -3/ order moment of particle temperature

4! – population density function, no m-3 K-1

55 parameter in Eq.(1),

, , 5 5

, 5 ' # , ' #

# 5 '

5 parameter in Eq.(1),

, , 5 5

5 , ' # 5' #

# 5 '

6! – volumetric flow rate, m3 s-1 7! – back-flow ratio

S - collision frequencie, (8-1) +! – temperature, K

3! – time, s 9! – volume, m3!

:! – axial variable, m

X - length of the fluidized bed (')

T – contact time, s Z! – random variable of

collision heat transfer P – viscosity, Pa s

H! – void fraction of the bed V2 – variance of the temperature

of particle population U! –! density, kg m3

! –! integral variable, kg m-3

;<=8#>?538!"4$!8<5@>8#>?538!

A! – gas

?4! – input

3C s VD, oCD

1st cell

9th cell

!"#$%&"''(!"#$%#&'!()*+,

*%-./0-.%-,,1$2-..-*Ę&31,

!"#$%&"''(!4-5Ħ5678,9!:;!75'

<*$=.!>-$%-,?.5!@)&A.%,A$)B' C?..%-,35-559!!:D!75

!"#$%&"''(!<*$=.!>-$%-,?.5

@)&A.%,A$)B'!C?..%-,35-559!!E!75

)*+,%-'"&"''./.$*&Ę012

!"#$%&"''(!4-5Ħ5678,9!:;!75'

<*$=.!>-$%-,?.5!@)&A.%,A$)B' C?..%-,35-559!!:F!75 Fig. 5.Transients of the variance of temperature of particle population

Modelling of Heat Transfer Processes with Compartment/Population Balance Model 2013 57 1–2 7

(6)

Tab. 1. The basic constitutive and process param-

eters used in simulation Parameter Basic value

Solid particles:sand Diameter,dp 2.54×10−4m

Density,ρp 2650 kg m−3

Specific heat,cp 835 J kg−1K−1 Thermal conductivity,kp 0.35 W m−1K−1 Volumetric flow rate,qp 1.5×10−5m3s−1 Mean inlet temperature,m 460°C

Gas:air Density,ρg 0.946 kg m−3

Specific heat,cg 1010 J kg−1K−1

Viscosity,µg 2.17×10−5Pa s

Thermal conductivity,kg 2.39×10−2W m−1K−1 Volumetric flow rate,qg 1.4×10−2m3s−1

Inlet temperature 25°C

Tube wall:stainless steel Diameter,Dl 0.0065 m

Mass,mw 1.2 kg

Specific heat,cw 465 J kg−1K−1 Thermal conductivity,kw 44 W m−1K−1

Heated medium:water Density,ρl 998 kg m−3

Specific heat,cl 4182 J kg−1K−1 Thermal conductivity,kl 0.606 W m−1K−1

Viscosity,µl 10−3Pa s

Volumetric flow rate,ql 1.5×10−5m3s−1

Inlet temperature 25°C

Fluidized bed Width,W 0.15 m

Length,L 0.9 m

Collision frequencies,Spp,Spw 103s−1, 10 s−1 Heat transfer efficienciesµpp,µpw 0.5, 0.8

Back flow ratio Rp,Rg,Rl 1, 0.1, 0.01

Heat transfer coefficients hpg 1.46×102

hwp 5.58×102

hwl 4.35×109

hgw 6.06×10−2

Conclusions

The compartment/population balance model, developed for describing heat transfer processes in gas-solid fluidized bed heat exchangers, and modelling the particle-particle and particle- surface heat transfer processes by collisions can be used effi- ciently for analysing the fluidized bed heat exchangers recov- ering heat from hot particles and heating some liquid flowing in a tube immersed in the bed. The model describes the tem- perature distribution of the particle population, and allows sep- arating the effects of the fluidizing gas-immersed surface and particle-immersed surface heat transfers. The second order mo- ment equation reduction, generated from the population balance equation has proved to be an efficient tool for studying the be- haviour of heat exchangers.

References

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Effects of collision induced alterations on the flow dynamics, Int. J. Heat Mass Transfer., 48, (2005), 1649.

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Subscripts and superscripts

g gas

in input l liquid

max maximal value min minimal value

p particle gp gas-particle

pp particle-particle pw particle-wall w wall gw gas-wall wl wall-liquid

Symbols

a surface area, m2 c specific heat, J kg−1K−1 d diameter (m)

W width of the bed, m D diameter of the tube, m

DT thermal diffusivity, DT =kwwcw,m2s−1 f probability density function

h heat transfer coefficient, W m−2K−1 k thermal conductivity, W m−1K−1 K number of cells

L length of fluidized bed (m) m – mass, kg Mk kthorder moment of particle temperature

mk normalised kthorder moment of particle temperature n population density function, no m−3K−1

pp parameter in Eq.(1), pp= mwcw

mpcp+mwcw

pw parameter in Eq.(1), pw= mpcp

mpcp+mwcw q volumetric flow rate, m3s−1

R back-flow ratio

S collision frequencie, s−1 T temperature, K

t time, s V volume, m3 x axial variable, m

X length of the fluidized bed, m θ contact time, s

ω random variable of collision heat transfer µ viscosity, Pa s

ε void fraction of the bed

σ2 variance of the temperature of particle population ρ density, kg m−3

τ integral variable, K

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